I never tried sion, but it seems it's just a slightly weaker version of altar's henchmen. CMIIW
Henchmen spells are incomplete version of the real spellbook path. That being said, hencmen can be build as an excellent mage without decalon books because there are some very useful spells on the henchmen minor spellbook path, like growth/shrink, storm, haste, slow, etc plus the path of the mage.
Because of path of the mage, henchmen is much much better mage compared to original FE's henchmen mage, because there are many good traits in path of the mage, the summoning line make the game very easy at harder difficulty. I assume scion can access this, if yes then mage scion is as good as henchmen, well..., maybe a slightly lesser version of it. The only different is the incomplete spells which henchmen has (though some are excellent spells)